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Reconciliation of Essential Process Parameters for an Enhanced Predictability of Arctic Stratospheric Ozone Loss and Its Climate Interactions : Volume 12, Issue 11 (27/11/2012)

By Von Hobe, M.

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Book Id: WPLBN0003988081
Format Type: PDF Article :
File Size: Pages 94
Reproduction Date: 2015

Title: Reconciliation of Essential Process Parameters for an Enhanced Predictability of Arctic Stratospheric Ozone Loss and Its Climate Interactions : Volume 12, Issue 11 (27/11/2012)  
Author: Von Hobe, M.
Volume: Vol. 12, Issue 11
Language: English
Subject: Science, Atmospheric, Chemistry
Collections: Periodicals: Journal and Magazine Collection (Contemporary), Copernicus GmbH
Historic
Publication Date:
2012
Publisher: Copernicus Gmbh, Göttingen, Germany
Member Page: Copernicus Publications

Description
Description: Forschungszentrum Jülich, Institute for Energy and Climate Research (IEK-7), Jülich, Germany. Significant reductions in stratospheric ozone occur inside the polar vortices each spring when chlorine radicals produced by heterogeneous reactions on cold particle surfaces in winter destroy ozone mainly in two catalytic cycles, the ClO dimer cycle and the ClO/BrO cycle. Chlorofluorocarbons (CFCs), which are responsible for most of the chlorine currently present in the stratosphere, have been banned by the Montreal Protocol and its amendments, and the ozone layer is predicted to recover to 1980 levels within the next few decades. During the same period, however, climate change is expected to alter the temperature, circulation patterns and chemical composition in the stratosphere, and possible geo-engineering ventures to mitigate climate change may lead to additional changes. To realistically predict the response of the ozone layer to such influences requires the correct representation of all relevant processes. The European project RECONCILE has comprehensively addressed remaining questions in the context of polar ozone depletion, with the objective to quantify the rates of some of the most relevant, yet still uncertain physical and chemical processes. To this end RECONCILE used a broad approach of laboratory experiments, two field missions in the Arctic winter 2009/10 employing the high altitude research aircraft M55-Geophysica and an extensive match ozone sonde campaign, as well as microphysical and chemical transport modelling and data assimilation. Some of the main outcomes of RECONCILE are as follows: (1) vortex meteorology: the 2009/10 Arctic winter was unusually cold at stratospheric levels during the six-week period from mid-December 2009 until the end of January 2010, with reduced transport and mixing across the polar vortex edge; polar vortex stability and how it is influenced by dynamic processes in the troposphere has led to unprecedented, synoptic-scale stratospheric regions with temperatures below the frost point; in these regions stratospheric ice clouds have been observed, extending over >106km2 during more than 3 weeks. (2) Particle microphysics: heterogeneous nucleation of nitric acid trihydrate (NAT) particles in the absence of ice has been unambiguously demonstrated; conversely, the synoptic scale ice clouds also appear to nucleate heterogeneously; a variety of possible heterogeneous nuclei has been characterised by chemical analysis of the non-volatile fraction of the background aerosol; substantial formation of solid particles and denitrification via their sedimentation has been observed and model parameterizations have been improved. (3) Chemistry: strong evidence has been found for significant chlorine activation not only on polar stratospheric clouds (PSCs) but also on cold binary aerosol; laboratory experiments and field data on the ClOOCl photolysis rate and other kinetic parameters have been shown to be consistent with an adequate degree of certainty; no evidence has been found that would support the existence of yet unknown chemical mechanisms making a significant contribution to polar ozone loss. (4) Global modelling: results from process studies have been implemented in a prognostic chemistry climate model (CCM); simulations with improved parameterisations of processes relevant for polar ozone depletion are evaluated against satellite data and other long term records using data assimilation and detrended fluctuation analysis. Finally, measurements and process studies within RECONCILE were also applied to the winter 2010/11, when special meteorological conditions led to the highest chemical ozone loss ever observed in the Arctic. In addition to quantifying the 2010/11 ozone loss and to understand its causes including possible

Summary
Reconciliation of essential process parameters for an enhanced predictability of Arctic stratospheric ozone loss and its climate interactions

Excerpt
Sovde, O. A., Orsolini, Y. J., Jackson, D. R., Stordal, F., Isaksen, S. A., and Rognerud, B.: Estimation of Arctic ozone loss in winter 2006/2007 using a chemical transport model and data assimilation., Q. J. Roy. Meteor. Soc., 137, 118–128, 2011.; Spang, R., Groo{ß}, J. U., Günther, G., Von Hobe, M., Kalicinsky, C., Riese, M., Stroh, F., Ungermann, J., Gerber, D., Moyna, B. P., Oldfield, M. L., Reburn, W. J., Siddans, R., Kerridge, B. J., Oelhaf, H., and Woiwode, W.: Final Report of the PremierEX Study, ESA, ESTEC, Netherlands, 2011.; SPARC: SPARC Report No. 5, Chemistry-Climate Model Validation, SPARC, 2010.; Stolarski, R. S., Krueger, A. J., Schoeberl, M. R., McPeters, R. D., Newman, P. A., and Alpert, J. C.: Nimbus-7 satellite measurements of the springtime Antarctic ozone decrease, Nature, 322, 808–811, 1986.; Stroh, F., Groo{ß}, J. U., Heinecke, F., von Hobe, M., Suminska-Ebersoldt, O., Volk, C. M., and Wegner, T.: Polar vortex ClOx chemistry from RECONCILE: ClO and ClO dimer measurements, Quadrennial Ozone Symposium, Toronto, Canada, L08502, doi:10.1029/2009GL037524, 2012.; Struthers, H., Bodeker, G. E., Austin, J., Bekki, S., Cionni, I., Dameris, M., Giorgetta, M. A., Grewe, V., Lefèvre, F., Lott, F., Manzini, E., Peter, T., Rozanov, E., and Schraner, M.: The simulation of the Antarctic ozone hole by chemistry-climate models, Atmos. Chem. Phys., 9, 6363–6376, doi:10.5194/acp-9-6363-2009, 2009.; Sumi\'{n}ska-Ebersoldt, O., Lehmann, R., Wegner, T., Groo{ß}, J.-U., Hösen, E., Weigel, R., Frey, W., Griessbach, S., Mitev, V., Emde, C., Volk, C. M., Borrmann, S., Rex, M., Stroh, F., and von Hobe, M.: ClOOCl photolysis at high solar zenith angles: analysis of the RECONCILE self-match flight, Atmos. Chem. Phys., 12, 1353–1365, doi:10.5194/acp-12-1353-2012, 2012.; Tilmes, S., Müller, R., and Salawitch, R. J.: The sensitivity of polar ozone depletion to proposed geoengineering schemes, Science, 320, 1201–1204, 2008.; Tsias, A., Wirth, M., Carslaw, K. S., Biele, J., Mehrtens, H., Reichardt, J., Wedekind, C., Weiss, V., Renger, W., Neuber, R., von Zahn, U., Stein, B., Santacesaria, V., Stefanutti, L., Fierli, F., Bacmeister, J., and Peter, T.: Aircraft lidar observations of an enhanced type Ia polar stratospheric clouds during APE-POLECAT, J. Geophys. Res, 104, 23961–23969, 1999.; Tuck, A. F., Watson, R. T., Condon, E. P., Margitan, J. J., and Toon, O. B.: The planning and execution of ER-2 and DC-8 aircraft flights over Antarctica, August and September 1987, J. Geophys. Res., 94, 11181–11222, 1989.; Turner, J., Comiso, J. C., Marshall, G. J., Lachlan-Cope, T. A., Bracegirdle, T., Maksym, T., Meredith, M. P., Wang, Z., and Orr,&

 

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